A New Synthetic Method of Alkyl Carbonocyanidate N-Oxides

DOI: 10.1246/bcsj.58.2519

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2519 - 2522 (1985)

Update date:2022-08-04

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Authors:

Shimizu, Tomio

Hayashi, Yoshiyuki

Teramura, Kazuhiro

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Article abstract of DOI:10.1246/bcsj.58.2519

A thermal decomposition of dimethyl nitromalonate to bis(carbomethoxy)furoxan was observed at about 170 deg C.In the presence of dipolarophiles, an intermediate, methyl carbonocyanidate N-oxide MeOCOCN->O, could be trapped as cycloadducts in good yields b

Full text of DOI:10.1246/bcsj.58.2519

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