Total synthesis of FK-506. Part 1: Construction of the C16-C34 fragment

DOI: 10.1016/S0040-4020(97)00865-X

Source and publish data:

Tetrahedron p. 13221 - 13256 (1997)

Update date:2022-08-03

Topics:

Authors:

Ireland, Robert E.

Liu, Longbin

Roper, Thomas D.

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Article abstract of DOI:10.1016/S0040-4020(97)00865-X

The C23-C27 1,3-diol was constructed via either Brown's crotylation - osmylation or regio- and stereoselective opening of an 2,9-anhydro-β-ribofuranoside derived from D-xylofuranose. Lewis acid catalyzed epoxide opening with a protected lithiofurfural alc

Full text of DOI:10.1016/S0040-4020(97)00865-X

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