Synthesis of enantiopure (2R,3aS,7aS)-2-ethyloctahydroindol-6-one and its Fischer indolization

DOI: 10.1016/S0957-4166(97)00379-0

Source and publish data:

Tetrahedron Asymmetry p. 3143 - 3151 (1997)

Update date:2022-08-04

Topics:

Authors:

Bonjoch, Josep

Catena, Juanlo

Terricabras, Dolors

Fernandez, Joan-Carles

Lopez-Canet, Meritxell

Valls, Nativitat

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Article abstract of DOI:10.1016/S0957-4166(97)00379-0

A diastereoselective synthesis of (-)-2-ethyloctahydroindol-6-one 12 starting from O-methyl-L-tyrosine 1 is described. The process first involves the synthesis of enantiopure (-)-1-(4-methoxyphenyl)-2-butylamine 8, which, after Birch reduction, N-benzylat

Full text of DOI:10.1016/S0957-4166(97)00379-0

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