Formation of cisoid-η4(5e)-Butadienylrhenium Complexes by Coupling of Alkene and Alkyne Ligands

DOI: 10.1039/c39950000767

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 767 - 768 (1995)

Update date:2022-07-30

Topics:

Authors:

Dossett, Stephen J.

Green, Michael

Mahon, Mary F.

McInnes, Jacqueline

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950000767

The reaction of the η²(4e)-bonded alkyne complexes 2-RC2Ph)(η-C5H5)> (R = Me or Ph) with o-diphenylphosphinostyrene and 2 equiv.AgBF4 in THF surprisingly affords HBF4, AgBr and excellent yields of the cationic η⁴(5e)-butadienyl complexes 3-(η-C5H5)>; the methyl-substituted system being structurally characterised by a single-crystal X-ray diffraction study.

Full text of DOI:10.1039/c39950000767

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Re(C₅H₅)(C(C₆H₅)C(CH₃)CHCHC₆H₄P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-) = [Re(C₅H₅)(C(C₆H₅)C(CH₃)CHCHC₆H₄P(C₆H₅)2)]BF₄

Cas No:199395-08-9

R&D Labs maybe for 199395-08-9

Hubei Sibo Technology Co.,Ltd.

Contact:0715-6597222

Address:Pan Jia Wan fan Lake Chemical Industrial Park ,Xianning City, Hubei, China
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian

Relevant to this article

Highly efficient formation of halodiazoacetates and their use in stereoselective synthesis of halocyclopropanes

Doi:10.1039/b814374a
(2008)
Doi:10.1002/hlca.19780610812
(1978)
Multistage Reactive Transmission-Mode Desorption Electrospray Ionization Mass Spectrometry

Doi:10.1007/s13361-015-1171-5
(2015)
Synthesis and biological analysis of benzazol-2-yl piperazine sulfonamides as 11β-hydroxysteroid dehydrogenase 1 inhibitors

Doi:10.1016/j.bmcl.2013.07.047
(2013)
Production of alkanes from lignin-derived phenolic compounds over in situ formed Ni catalyst with solid acid

Doi:10.1246/cl.150066
(2015)
Synthesis of ABC 3-miktoarm star terpolymers from a trifunctional initiator by combining ring-opening polymerization, atom transfer radical polymerization, and nitroxide-mediated radical polymerization

Doi:10.1021/ma036010c
(2004)

Article Doi