Tetrahedron Asymmetry p. 3283 - 3292 (1997)
Update date:2022-09-26
Topics:
Garcia Ruano, Jose L.
Gonzalez-Vadillo, Ana M.
Maestro, M. Carmen
The influence of the stereogenic hydroxylic carbon at the δ-position of the carbonyl group in 1,5-bis(p-tolylsulfinyl)-4-hydroxy-2-pentanone 1 and 2,6-bis(p-tolylsulfinyl)-5-hydroxy-3-hexanones 2 on the stereochemical course of DIBALH and DIBALH/ZnBr2 reductions has been studied. In contrast with the DIBALH reductions of β-hydroxyketones, that are monitored by the hydroxylic stereogenic carbon, the presence of the sulfinyl group determines a complete 1,3-induction of the sulfur centre.
View MoreAnhui Gusheng Import&Export CO.,LTD
Contact:86-551-63662296
Address:Jinzhai Road NO.162 ,hefei, china
Xiamen Hisunny Chemical Co.,Ltd
website:http://www.hisunnychem.com
Contact:+86-592-3327115
Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)
Contact:+86-523-86818997
Address:Taizhou,Jiangsu Province,CHINA
Doi:10.1016/j.tet.2020.131410
(2020)Doi:10.1021/jo01260a042
(1969)Doi:10.1021/jo01261a021
(1969)Doi:10.1246/bcsj.41.748
(1968)Doi:10.1021/jo971449m
(1998)Doi:10.1021/jm970296s
(1998)
