Tetrahedron Asymmetry p. 3283 - 3292 (1997)
Update date:2022-09-26
Topics:
Garcia Ruano, Jose L.
Gonzalez-Vadillo, Ana M.
Maestro, M. Carmen
The influence of the stereogenic hydroxylic carbon at the δ-position of the carbonyl group in 1,5-bis(p-tolylsulfinyl)-4-hydroxy-2-pentanone 1 and 2,6-bis(p-tolylsulfinyl)-5-hydroxy-3-hexanones 2 on the stereochemical course of DIBALH and DIBALH/ZnBr2 reductions has been studied. In contrast with the DIBALH reductions of β-hydroxyketones, that are monitored by the hydroxylic stereogenic carbon, the presence of the sulfinyl group determines a complete 1,3-induction of the sulfur centre.
View MoreSanming Coffer Fine Chemical Industrial Co., Ltd
website:http://www.cofferxm.com/
Contact:+86-598-5853979
Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Yangzhou Zhongbao Pharmaceutical Co.,Ltd
Contact:+86-514-88290838
Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Contact:+91 - 22 - 26355700
Address:17, Lotus Business Park, Andheri West
Shanghai Rich Chemicals Co., Ltd
website:http://www.richchemical.com
Contact:+86-21-20255798
Address:Pudong Shanghai,China
Beijing Apis Biotechnology Co., Ltd.
Contact:86-010-67856775-8551
Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Doi:10.1016/j.tet.2020.131410
(2020)Doi:10.1021/jo01260a042
(1969)Doi:10.1021/jo01261a021
(1969)Doi:10.1246/bcsj.41.748
(1968)Doi:10.1021/jo971449m
(1998)Doi:10.1021/jm970296s
(1998)
