
Tetrahedron Letters p. 8781 - 8784 (1997)
Update date:2022-08-03
Topics:
Roush, William R.
Barda, David A.
Three of the four diastereomeric spirotetronates (2, 19 and 24) corresponding to the quartromicins were synthesized by a sequence featuring the intramolecular Diels-Alder reaction of 3. An olefin isomerization pathway accounts for fonmation of the second most abundant cycloadduct, 16.
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(1997)