
Phosphorus, Sulfur and Silicon and the Related Elements p. 173 - 180 (1997)
Update date:2022-08-03
Topics:
Ghany, H. Abdel
5,5-Dibromo-3-phenyl-2-thioxo-4-thiazolidinone 2, was reacted with bidentates, or with CS2 and active methylenes under PTC conditions to afford the corresponding spiro compounds 4a-h or 5a-e. 5-ethoxymethylene-3-phenyl-2-thioxo-4-thiazolidinone 3 was treated with diamino or aminomercaplo compounds to give the desired products 6a-d. Treatment of compound 3 with malononitrile gave compound 7. Reaction of compound 7 with some active methylenes affords the corresponding spiro cyclopentenes 8a-c.
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Doi:10.1021/jo00837a714
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(2020)