Selective one carbon-carbon bond formation reaction of zirconacyclopentadienes with aryl iodides or alkynyl iodides

DOI: 10.1016/S0040-4020(97)10295-2

Source and publish data:

Tetrahedron p. 715 - 726 (1998)

Update date:2022-09-26

Topics:

Authors:

Takahashi, Tamotsu

Sun, Wen-Hua

Xi, Chanjuan

Ubayama, Haruka

Xi, Zhenfeng

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Article abstract of DOI:10.1016/S0040-4020(97)10295-2

Reaction of zirconacyclopentadienes with one equiv or two equiv of aryl iodides in the presence of CuCl and DMPU afforded mono-arylated diene derivatives in high yields with high selectivities. Treatment of zirconacyclopentadienes with one equiv of 2-thie

Full text of DOI:10.1016/S0040-4020(97)10295-2

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Product name:4-iodo-7-(1-naphthyl)-5,6-dipropyldeca-(4Z,6Z)-4,6-diene

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