Simple design for the construction of complex gibberellin framework - Stereoselective synthesis of a possible key intermediate to GA12 via Pd2+-promoted cycloalkenylation reaction

DOI: 10.1016/0040-4020(95)00341-5

Source and publish data:

Tetrahedron p. 6927 - 6940 (1995)

Update date:2022-07-31

Topics:

Authors:

Toyota, Masahiro

Wada, Toshihiro

Nishikawa, Youichi

Yanai, Keiko

Fukumoto, Keiichiro

Kabuto, Chizuko

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Article abstract of DOI:10.1016/0040-4020(95)00341-5

A successful design for the construction of C₂₀ gibberellin framework has been described. The key features of the synthesis are as follows: (a) Pd²⁺-promoted cycloalkenylation reaction (6→5) and (b) intramolecular Diels-Alder reaction (4→3).

Full text of DOI:10.1016/0040-4020(95)00341-5

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