Simple design for the construction of complex gibberellin framework - Stereoselective synthesis of a possible key intermediate to GA12 via Pd2+-promoted cycloalkenylation reaction

DOI: 10.1016/0040-4020(95)00341-5

Source and publish data:

Tetrahedron p. 6927 - 6940 (1995)

Update date:2022-07-31

Topics:

Authors:

Toyota, Masahiro

Wada, Toshihiro

Nishikawa, Youichi

Yanai, Keiko

Fukumoto, Keiichiro

Kabuto, Chizuko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)00341-5

A successful design for the construction of C₂₀ gibberellin framework has been described. The key features of the synthesis are as follows: (a) Pd²⁺-promoted cycloalkenylation reaction (6→5) and (b) intramolecular Diels-Alder reaction (4→3).

Full text of DOI:10.1016/0040-4020(95)00341-5

Products guided by the article

Product name:[4-Allyl-4-(2-methoxymethoxy-ethyl)-cyclohexa-1,5-dienyloxy]-trimethyl-silane

Cas No:206866-11-7

R&D Labs maybe for 206866-11-7

Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD

Relevant to this article

Stereoselective synthesis of (2S, 3R)-N-Boc-3 hydroxyglutamic acid

Doi:10.1016/S0040-4039(98)00360-8
(1998)
Stereoselective Synthesis of (2S,3S)-2-Benzyl-2-hydroxy-3-(3,4-methylenedioxybenzyl)-γ-butyrolactone from L-(+)-Arabinose via a Carissanol-type of Lignan

Doi:10.1271/bbb.62.521
(1998)
Heck Arylation of 1,2-Cyclohexanedione and 2-Ethoxy-2-cyclohexenone

Doi:10.1021/jo980221b
(1998)
Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

Doi:10.1016/S0040-4039(98)00338-4
(1998)
Synthesis and binding-analysis of 5E-[19-(2-bromoacetoxy)methyl]25- hydroxyvitamin D₃ and 5E-25-hydroxyvitamin D₃-19-methyl[(4-azido-2- nitro)phenyl]glycinate: Novel C₁₉-modified affinity and photoaffinity analogs of 25-hydroxyvitamin D₃

Doi:10.1016/S0039-128X(98)00009-9
(1998)
Toward a practical synthesis of morphine. The first several generations of a radical cyclization approach

Doi:10.1055/s-1998-5931
(1998)

Article Doi