Tetrahedron p. 7273 - 7292 (1998)
Update date:2022-08-04
Topics:
Beil, Winfried
Jones, Peter G.
Nerenz, Frank
Winterfeldt, Ekkehard
The group and face-selective cycloaddition of the enantiopure cyclopentadiene 4 to the tyrosine-related spirocylohexadienone 10 provided a high yield of the enantiomencally pure cyclohexadienone 11. Stereoselective transformations at the remaining double bond followed by a thermal retro- process, finally giving rise to the chromophore of the marine agelorin antibiotics isolated from the sponge Agelas oroides Schmidt.
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