NMR evidence for formation of new alcohol rhenium complexes as intermediates in ionic hydrogenations of carbonyl groups with systems composed of ReH2(NO) (CO) (PR3)2 (R = Pri, CH3, OPri) an

DOI: 10.1016/S0020-1693(98)00013-9

Source and publish data:

Inorganica Chimica Acta p. 122 - 126 (1998)

Update date:2022-09-26

Topics:

Authors:

Bakhmutov, Vladimir I.

Vorontsov, Evgenii V.

Antonov, Dmitry Yu.

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Article abstract of DOI:10.1016/S0020-1693(98)00013-9

Low-temperature hydrogenations of benzaldehyde and acetone by systems ReH₂(CO) (NO) (PR₃)₂/CF₃COOH in CD₂Cl₂ with R = Prⁱ (1a), CH₃ (1b) and OPrⁱ (1c) resul

Full text of DOI:10.1016/S0020-1693(98)00013-9

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Product name:ReH(CO)(NO)(P(OCH(CH₃)2)3)2(C₆H₅CH₂OH)⁽¹⁺⁾*CF₃CO₂^(1-)=[ReH(CO)(NO)(P(OCH(CH₃)2)3)2(C₆H₅CH₂OH)]CF₃CO₂

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