Tetrahedron p. 9791 - 9798 (1998)
Update date:2022-08-04
Topics:
Sengupta, Saumitra
Sen Sarma, Debarati
Mondal, Somnath
Starting from 'chiral-pool' derived γ-amino-β-ketosulfones, a facile synthesis of enantio-pure α-amino ketones has been developed via an α- alkylation-desulfonation sequence. Extension of this methodology to enantiopure α-acetoxy ketone synthesis, however, have met with limited success.
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