Synthesis, characterization and thermal investigation of some metal complexes derived from new schiff base ligands

Article abstract of DOI:10.1080/00945719809349413

A new series of complexes of palladium(II), oxovanadium(IV) and zinc(II) ions with N-(3,4-dihydroxysalicylidene)-3,5-di(tert-butyl)-4-hydroxyaniline(HL) and N-(4,6-dihydroxysalicylidene-3,5-di(tert-butyl)-4-hydroxyaniline (HL¹) have been prepared and characterized by elemental analyses, electronic absorption spectral data, infrared, magnetic moment and molar conductance data. In order to determine the structures of the ligands with their palladium(II) and zinc(II) complexes, ¹H and ¹³C NMR spectra were obtained. All compounds were found to be non-electrolytes in DMSO (～1 mM). The thermal behaviour of the ligands and their complexes have been investigated using thermogravimetric techniques (TG and DTA). The thermogravimetric data agree with the results of the analytical and spectral analyses. The degradation of the hydrated complexes occurs in several steps with the dehydration reaction followed by complete decomposition to the corresponding metal oxides.

Full text of DOI:10.1080/00945719809349413

This article was downloaded by: [University of Cambridge]
On: 17 October 2014, At: 04:15
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsrt19
Synthesis, Characterization and
Thermal Investigation of Some
Metal Complexes Derived from
New Schiff Base Ligands
Mehmet Tümer a , Hüseyin Köksal a & Selahattin
Serin a b
a K. Maraş Sütçüimam University, Faculty of Science
and Arts, Department of Chemistry , K. Maraş,
46100, Turkey
b Çukurova University, Faculty of Science and Arts,
Department of Chemistry , Balcali, 01330, Adana,
Turkey
Published online: 14 Apr 2008.
To cite this article: Mehmet Tümer , Hüseyin Köksal & Selahattin Serin (1998)
Synthesis, Characterization and Thermal Investigation of Some Metal Complexes
Derived from New Schiff Base Ligands, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 28:8, 1393-1404, DOI: 10.1080/00945719809349413
To link to this article: http://dx.doi.org/10.1080/00945719809349413
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views

expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions