Natural Product Research p. 2173 - 2178 (2020)
Update date:2022-07-29
Topics:
Narala, Siva Ganesh
Nagalatha
Venkat Narsaiah
A stereoselective total synthesis of 16-membered C2-symmetric macrodiolide Pyrenophorol, Tetrahydropyrenophorol and 4,4-diacetylpyrenophorol have been accomplished. The synthesis started from commercially available L-Aspartic acid and the key reactions involved are regioselective epoxide opening, CBS reduction, Pinnick oxidation and Mitsunobu dilactonization.
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