Tetrahedron Letters p. 6929 - 6930 (1996)
Update date:2022-08-03
Topics:
Fleming, Ian
Lee, Duckhee
TMS chloride raises the yield in the conjugate addition of silylcuprates and zincates to β-unsubstituted enones, and Si-to-OH conversion is possible using the 2-methylbut-2-enyl(diphenyl)silyl group in the presence of highly nucleophilic alkenes. Both reactions are used in a synthesis of lavandulol.
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