PhCH=P(MeNCH2CH2)3N: A novel ylide in the Wittig reaction

DOI: 10.1016/S0040-4039(98)02157-1

Source and publish data:

Tetrahedron Letters p. 9331 - 9334 (1998)

Update date:2022-07-31

Topics:

Authors:

Wang, Zhigang

Verkade, John G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)02157-1

The title semi-stabilized ylide prepared from the commercially available non-ionic superbase P(MeNCH₂CH₂)₃N reacts with aldehydes to give alkenes in high yield with surprisingly quantitative E selectivity.

Full text of DOI:10.1016/S0040-4039(98)02157-1

Products guided by the article

Product name:1-benzylidene-2,8,9-trimethyl-2,5,8,9-tetraaza-1λ⁵-phospha-bicyclo[3.3.3]undecane

Cas No:220229-03-8

R&D Labs maybe for 220229-03-8

Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)

Contact:+86-027-84466317 __ +86-15387123698

Address:wuhan - china
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Chuzhou Baiao Biologhy S&T Co., Ltd.

Contact:+86-25-83212599；+86-25-83212699 13705185959

Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Chengdu NoVi Biotechnology Co., Ltd.(expird)

Contact:13551243286/028-81458053

Address:NO.168-1-224 JULONG ROAD WUHOU DISTRICT, CHENGDU CITY,SICHUAN PROVINCE
Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China

Relevant to this article

Doi:10.1039/jr9520004657
(1952)
Antiproliferative activity of novel thiophene and thienopyrimidine derivatives

Doi:10.1055/s-0033-1358679
(2014)
1-Diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

Doi:10.1107/S0108270196009109
(1996)
Catalytic Regioselective Olefin Hydroarylation(alkenylation) by Sequential Carbonickelation-Hydride Transfer

Doi:10.1021/jacs.1c03228
(2021)
Synthesis and in vitro antitumour activity of 4(R)-methyl-3-O-phosphonomethyl-α-L-threose nucleosides

Doi:10.1016/j.ejmech.2021.113513
(2021)
Quinolone-based IMPDH inhibitors: Introduction of basic residues on ring D and SAR of the corresponding mono, di and benzofused analogues

Doi:10.1016/S0960-894X(02)00945-9
(2003)

Article Doi