PhCH=P(MeNCH2CH2)3N: A novel ylide in the Wittig reaction

DOI: 10.1016/S0040-4039(98)02157-1

Source and publish data:

Tetrahedron Letters p. 9331 - 9334 (1998)

Update date:2022-07-31

Topics:

Authors:

Wang, Zhigang

Verkade, John G.

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Article abstract of DOI:10.1016/S0040-4039(98)02157-1

The title semi-stabilized ylide prepared from the commercially available non-ionic superbase P(MeNCH₂CH₂)₃N reacts with aldehydes to give alkenes in high yield with surprisingly quantitative E selectivity.

Full text of DOI:10.1016/S0040-4039(98)02157-1

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