Tetrahedron Letters p. 2793 - 2796 (1999)
Update date:2022-08-05
Topics:
Yamanoi, Shigeo
Matsumoto, Takashi
Suzuki, Keisuke
Allylzirconium species, generated by hydrozirconation of allenes, react with 1-iodoalkynes in the presence of methylaluminoxane (MAO) to give the substitution products of the iodide by an allyl group. Labelling study for 2- (iodoethynyl)naphthalene suggested that the reaction involves allylzirconation of iodoalkynes to generate an alkylidene carbenoid that undergoes 1,2-rearrangement.
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