Acta Crystallographica, Section C: Crystal Structure Communications p. 545 - 547 (1999)
Update date:2022-08-05
Topics:
Hoekelek, Tuncer
Necefoglu, Hacali
The title compound, [Co(C7H5O2)2(C6H 6N2O)2(H2O)2], is a crystallographically centrosymmetric monomeric complex in which pyridine N, and carboxylate and water O atoms form a tetragonally Jahn-Teller-distorted octahedron about the CoII ion, with bond distances of 2.150 (1), 2.085 (1) and 2.141 (1) A, respectively. There is a hydrogen bond between nicotinamide N and O atoms [N...O 2.976 (2) A], and the non-coordinated O atom of the carboxylate group and that of nicotin-amide form hydrogen bonds with water O atoms [O...O 2.580 (2) and 2.911 (1) A, respectively].
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