Tetrahedron p. 8497 - 8508 (1999)
Update date:2022-09-26
Topics:
Fernandez, Raul
Castillon, Sergio
The gem-difluoronucleosides 1 and 2, pyranosyl analogues of gemcitabine, have been synthesized from D-mannose and D-glucose respectively. The key steps were the formation of the difluoromethylene group by reaction of the corresponding ulose with DAST, and the glycosylation.
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