Angewandte Chemie - International Edition p. 4428 - 4433 (2020)
Update date:2022-08-03
Topics: Yield Catalyst Selectivity Ligand Kinetics coordination complex Reaction Mechanism Reducing Agent Homolytic Cleavage Substrate Oxidizing agent Electron Paramagnetic Resonance (EPR) Stoichiometry Thermodynamics Radical intermediate redox reaction Radical trap
Li, Jinxia
Li, Ping
Liu, Run-Zhou
Liu, Xian-Guan
Qu, Shuanglin
Sun, Jun
Zhang, Bo
A simple and efficient protocol to generate amidyl radicals from amine functionalities through a manganese-mediated atom-transfer reaction has been developed. This approach employs an earth-abundant and inexpensive manganese complex, Mn2(CO)
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