Journal of Organometallic Chemistry p. 193 - 198 (1995)
Update date:2022-08-05
Topics:
Chatani, Naoto
Tokuhisa, Hideo
Kokubu, Ichiro
Fujii, Satoru
Murai, Shinji
Co2(CO)8-catalyzed reaction of aromatic aldehydes with hydrosilanes under CO as 1 atm results in incorporation of CO into the carbonyl carbon atom of aldehydes to give arylethane-1,2-diol disilyl ethers as the main product.The reaction of aliphatic aldehydes gives similar products, only with low yields.Keywords: Cobalt; Silicon; Hydrosilane; Aldehyde; Carbon monoxide; Oxymethylation
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