Tetrahedron p. 1161 - 1169 (1981)
Update date:2022-08-04
Topics:
Laguerre, Michel
Grignon-Dubois, Micheline
Dunogues, Jacques
A simple general route for the conversion of olefins to gem-disilylcyclopropanes, involving the dichlorocyclopropanation of the double bond followed by silylation using the Me3SiCl/Li/THF reagent at 0-10 deg C, is described.Acetylation of bicyclic derivatives thus obtained constitutes an original synthesis of cycloalkylidene ketones by a process more convenient than those previously used, and also provides new acetyl dihydrofurans.
View MoreContact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
Suzhou HeChuang Chemical Co.,Ltd.
Contact:+86-512-88800520
Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Huaian Double Win Chemicals Co.,Ltd.
Contact:+86-13511538872
Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
Contact:0571-
Address:zhejing
Contact:86-25-84683399
Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Doi:10.3987/COM-13-S(S)32
(2014)Doi:10.1021/acs.orglett.9b02863
(2019)Doi:10.1021/np049642g
(2005)Doi:10.1246/cl.1983.1499
(1983)Doi:10.3987/COM-99-8837
(2000)Doi:10.1007/BF01046678
()
