Tetrahedron Letters p. 5835 - 5838 (1986)
Update date:2022-08-04
Topics:
Runge, Andreas
Sander, Wolfram
Flash vacuum pyrolysis and matrix-isolation studies of 6-bromo-6-(trimethylstannyl)bicyclo<3.1.0>hexane (1) gave evidence for the formation of 1,2-cyclohexadiene (2) from this precursor.At high temperatures (>600 deg C) 2 is not stable and fragmentates to 1-butene-3-yne (4) and ethylene.
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