Highly efficient photochemical addition of tertiary amines to electron deficient alkenes. Diastereoselective addition to (5R)-5-menthyloxy-2[5H]- furanone

DOI: 10.1016/S0040-4039(99)00451-7

Source and publish data:

Tetrahedron Letters p. 3169 - 3172 (1999)

Update date:2022-08-05

Topics:

Authors:

Bertrand, Samuel

Glapski, Cedric

Hoffmann, Norbert

Pete, Jean-Pierre

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Article abstract of DOI:10.1016/S0040-4039(99)00451-7

Tertiary amines derived from pyrrolidines can be added very efficiently (isolated yields up to 94%) to (5R)-5-mentyloxy-2[5H]-furanone. The addition, which follows a radical chain mechanism initiated by a photoinitiated electron transfer (PET) from the te

Full text of DOI:10.1016/S0040-4039(99)00451-7

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