Journal of the American Chemical Society p. 1087 - 1093 (1982)
Update date:2022-08-05
Topics:
Marcello
Martell
This study reports the first detailed kinetic measurements of the pyridoxal and pyridoxal-metal-ion-catalyzed dealdolation of threonine, beta -hydroxyleucine, and beta -hydroxyvaline. The rate constants of these model system reactions have now been determined and a probable reaction mechanism is proposed.
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