Journal of the American Chemical Society p. 2490 - 2493 (1982)
Update date:2022-07-29
Topics:
Bates, Hans Aaron
Tetrahydrofuran-2-carboxylic acids 1, 3, and 5 readily decarbonylate in 96percent sulfuric acid, generating stable oxonium ions 2, 4, and 6, respectively.Analogously, tetrahydropyran-2-carboxylic acids 7, 9, 12, and 14a produce oxonium ions 8, 10, 13, and 15, respectively.These oxonium ions are quite stable, with the exception of 10, which partially isomerizes to 11, and 13, which rearranges to ions 17 and 21.Details in the transformation of oxonium ion 15 into lactone 23 by way of open chain acid 22a were elucidated.
View MoreZouping Mingxing Chemical Co.,Ltd.
website:http://www.zoutong.com.cn
Contact:86-543-2240068 2240067
Address:428 Daixi Third Road Zouping County Shandong Province China
Hefei TNJ chemical industry co.,ltd
website:https://www.tnjchem.com
Contact:+86-551-65418695
Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Contact:+86-25-52346955
Address:199,JIANYE ROAD,NANJING,CHINA
China Synchem Technology Co.,Ltd
website:http://www.cnsynchem.com
Contact:+86-0552-4929311
Address:No.217 Daqing Road
Chuzhou Baiao Biologhy S&T Co., Ltd.
Contact:+86-25-83212599;+86-25-83212699 13705185959
Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Doi:10.1016/S0960-894X(01)00079-8
(2001)Doi:10.1021/acs.orglett.8b00814
(2018)Doi:10.1021/jo00174a033
(1983)Doi:10.1016/S0040-4039(01)80105-2
(1984)Doi:10.1021/jo001644s
(2001)Doi:10.1134/S1070363207090253
(2007)