A New Synthetic Route to Electrophilic Cyclopropane Derivatives from Olefins

DOI: 10.1246/bcsj.54.2539

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2539 - 2540 (1981)

Update date:2022-07-31

Topics:

Authors:

Kawabata, Nariyoshi

Yano, Shinji

Hashimoto, Jiro

Yoshida, Jun-ichi

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Article abstract of DOI:10.1246/bcsj.54.2539

1,1-Bis(alkoxycarbonyl)-, 1-alkoxycarbonyl-1-cyano-, and 1,1-dicyanocyclopropane derivatives were obtained in 10-99percent yields by the reaction of Br2C(COOR)2, Br2C(CN)(COOR), and KBr4, respectively, with olefins and Cu2Br2 in dimethyl sulfox

Full text of DOI:10.1246/bcsj.54.2539

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