A New Synthetic Route to Electrophilic Cyclopropane Derivatives from Olefins

DOI: 10.1246/bcsj.54.2539

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2539 - 2540 (1981)

Update date:2022-07-31

Topics:

Authors:

Kawabata, Nariyoshi

Yano, Shinji

Hashimoto, Jiro

Yoshida, Jun-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.54.2539

1,1-Bis(alkoxycarbonyl)-, 1-alkoxycarbonyl-1-cyano-, and 1,1-dicyanocyclopropane derivatives were obtained in 10-99percent yields by the reaction of Br2C(COOR)2, Br2C(CN)(COOR), and KBr4, respectively, with olefins and Cu2Br2 in dimethyl sulfox

Full text of DOI:10.1246/bcsj.54.2539

Products guided by the article

Product name:1,1-bis(ethoxycarbonyl)-2-methyl-3-phenylcyclopropane

Cas No:344318-92-9

R&D Labs maybe for 344318-92-9

Jiangxi Dongxu Chemical Science & Technology Co.,Ltd

Contact:+86-791-86899381

Address:Nanchang, Jiangxi, China
Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Evershine Chemical CO Ltd

Contact:+86-571-87010026

Address:202, Zhenhua Road,
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
MENGNA

Contact:18698110882

Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city

Relevant to this article

Substituted salen-Ru(II) complexes as catalysts in the asymmetric cyclopropanation of styrene by ethyl diazoacetate: The influence of substituents and achiral additives on activity and enantioselectivity

Doi:10.1016/S0957-4166(01)00014-3
(2001)
From neutral Zn₄O₄ clusters to a cationic ZnO dimer in solution

Doi:10.1021/om061108b
(2007)
Doi:10.1016/S0040-4020(01)90764-1
(1971)
Pyrrolidine N-oxides by stereoselective addition of Grignard and lithium compounds to 4,5-dideoxy-2,3-O-isopropylidene-D-erythro-4-pentenose N-benzyl nitrone and subsequent Cope-House cyclization

Doi:10.1002/1099-0690(200104)2001:7<1293::AID-EJOC1293>3.0.CO;2-4
(2001)
Doi:10.1039/c29710000794
(1971)
On the mechanism of reactions of oncogenic n-acyloxypurines-III. Extent of radical participation¹ 1 This investigation was supported in part by Grants Number CA-08748 and CA-23622, awarded by the National Cancer Institute, DHEW. Ref. 20 is now designated as II in the series and Ref. 16 is designated as I.

Doi:10.1016/S0040-4020(01)93681-6
(1980)

Article Doi