Bulletin of the Chemical Society of Japan p. 3629 - 3636 (1995)
Update date:2022-08-03
Topics:
Hata, Eiichiro
Yamada, Tohru
Mukaiyama, Teruaki
Olefins with a terminal double bond or conjugated with aromatic nucleus are successfully nitrated into nitro olefins in good-to-high yields on treatment with nitrogen monoxide (NO) in 1,2-dichloroethane.Nitro alcohols formed as by-products are dehydrated to yield nitro olefins by the subsequent treatment with acidic activated alumina.By GC analysis, it was confirmed that an equimolar amount of nitro gas was evolved during the present nitration.A possible reaction pathway including the formation of nitro nitroso compounds, key intermediates, is described.The key intermediates are transformed into nitro olefins by reaction with nitrogen monoxide.
View MoreWeifang Yukai Chemical Co.,Ltd.
website:http://www.yukaichem.com/en.html
Contact:+86-536-8865336
Address:binhai economic development zone，262737 shangdong，china
Lanzhou huibang biological chemical technology Co., LTD
Contact:0931-7843964
Address:NO.2011,Yannan Road,Chengguan,
Xi'an North Information Industry Co., Ltd. Weilv Chemical Department
Contact:+86-29-88156413
Address:Jixiang Road 99 Xi'an Shaanxi Province
Daqing New Century Fine Chemical Co., Ltd.(expird)
Contact:010-57126694
Address:No.39, jinxing cun, honggang district
Tianjin Emulsion Science&Technology Development Co.,Ltd
Contact:13901380442
Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
Doi:10.3390/molecules26072081
(2021)Doi:10.1016/S0040-4039(01)94120-6
(1972)Doi:10.1134/S1070363215090108
(2015)Doi:10.1055/s-2005-916010
(2005)Doi:10.1021/jm00231a012
(1976)Doi:10.1016/j.ejmech.2017.04.010
(2017)
