Evidence for the Radical Pair Mechanism in 'Insertion' Reactions of Transition Metal Hydrides with Conjugated Dienes

DOI: 10.1039/c39860000312

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 312 - 314 (1986)

Update date:2022-08-04

Topics:

Authors:

Thomas, Marian J.

Shackleton, Thomas A.

Wright, Steven C.

Gillis, Daniel J.

Colpa, Johannes P.

Baird, Michael C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860000312

The compounds cpFe(CO)2H and HMn(CO)5 (cp = cyclopentadienyl) react with 1,3-dienes to give the 2-enylmetal products of 1,4-addition of the metal hydrides to the dienes; CIDNP studies indicate that the process involves a radical pair mechanism.

Full text of DOI:10.1039/c39860000312

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(η5-cyclopentadienyl)Fe(CO)2(CH2CH=C(CH3)2)

Cas No:38905-70-3

R&D Labs maybe for 38905-70-3

Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,
Compro Shijiazhuang Fine Chemical Co., Ltd

Contact:0086-311-89689838

Address:Economic and Technological Development Zone of Shijiazhuang,Hebei
SJZ THLD IMP & EXP CO LTD

website:http://www.truewingroup.com

Contact:86-311-66699812

Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Engineering Research Center of Pesticide, Heilongjiang Province

Contact:+86-451-86609001

Address:No.74 of Xuefu Road, Nangang District,

Relevant to this article

N, N′ -methyleno-didemnin A from the ascidian trididemnum solidum. Complete NMR assignments and confirmation of the imidazolidinone ring by strategic analysis of ¹ J _CH

Doi:10.1021/np100846s
(2011)
Synthesis and photochemical investigations of tetrasubstituted alkenes as molecular switches-the effect of substituents

Doi:10.1002/chem.201003559
(2011)
Tandem C-O and C-N Bonds Formation Through O-Arylation and [3,3]-Rearrangement by Diaryliodonium Salts: Synthesis of N-Aryl Benzo[1,2,3]triazin-4(1H)-one Derivatives

Doi:10.1021/acs.joc.5b01947
(2015)
TBHP/I₂-promoted oxidative coupling of azoles with benzyl compounds via cleavage of nonactivated C(sp³)-H bonds under solvent-free conditions

Doi:10.1055/s-0033-1338871
(2013)
5-FLUORO-SUBSTITUTED PYRAZOLES

Doi:10.1007/BF00958848
(1990)
A synthesis of phytosphingosines from D-galactose.

Doi:10.1039/j39660001876
(1966)

Article Doi