Evidence for the Radical Pair Mechanism in 'Insertion' Reactions of Transition Metal Hydrides with Conjugated Dienes

DOI: 10.1039/c39860000312

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 312 - 314 (1986)

Update date:2022-08-04

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Authors:

Thomas, Marian J.

Shackleton, Thomas A.

Wright, Steven C.

Gillis, Daniel J.

Colpa, Johannes P.

Baird, Michael C.

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Article abstract of DOI:10.1039/c39860000312

The compounds cpFe(CO)2H and HMn(CO)5 (cp = cyclopentadienyl) react with 1,3-dienes to give the 2-enylmetal products of 1,4-addition of the metal hydrides to the dienes; CIDNP studies indicate that the process involves a radical pair mechanism.

Full text of DOI:10.1039/c39860000312

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