Reactivity of mono- and di-methoxycarbonyl complexes of PdII towards amines and copper amine complexes: role of copper in the catalyzed palladium-copper oxidative carbonylation of amines

DOI: 10.1016/0022-328X(94)80174-6

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Journal of Organometallic Chemistry p. 249 - 252 (1994)

Update date:2022-07-30

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Giannoccaro, Potenzo

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Article abstract of DOI:10.1016/0022-328X(94)80174-6

The reactivity of mono- and di-methoxycarbonyl complexes of palladium of formula (n = 1 or 2; L2 = chelating ligand) towards amines in the presence of Cl or CuCl2 has been studied.The reactions yield N,N'-disubstituted ureas or carbamates, respectively.These results are compared with the dioxygen-induced carbonylative oxidation of amines catalyzed by palladium-based systems. Key words: Palladium; Copper; Carbonylation; Amine; Urea; Carbamate

Full text of DOI:10.1016/0022-328X(94)80174-6

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Reactivity of mono- and di-methoxycarbonyl complexes of PdII towards amines and copper amine complexes: role of copper in the catalyzed palladium-copper oxidative carbonylation of amines

DOI: 10.1016/0022-328X(94)80174-6

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(94)80174-6

Full text of DOI:10.1016/0022-328X(94)80174-6

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