Journal of the Chemical Society. Chemical communications p. 1726 - 1728 (1991)
Update date:2022-08-04
Topics:
Bleasdale, Christine
Golding, Bernard T.
McGinnis, Joseph
Mueller, Susanna
Watson, William P.
The use of 13C NMR spectroscopy to monitor the decomposition of <13CO>N-methyl-N-nitrosourea, and of 15N NMR spectroscopy to follow the decomposition of <15NH2>N-methyl-N-nitrosourea, both in aqueous phosphate buffer at pH 7, shows the initial product to be cyanate rather then carbamate; the cyanate reacts with phosphate to give carbamoyl phosphate.
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