An Indirect Method for Engaging Unactivated Alkenes as Effective Dienophiles in Regioselective Diels-Alder Reactions

DOI: 10.1021/jo00149a035

Source and publish data:

Journal of Organic Chemistry p. 141 - 142 (1983)

Update date:2022-08-04

Topics:

Authors:

Paquette, Leo A.

Crouse, Gary D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00149a035

Terminal alkenes and cyclic olefins can be made to enter into efficient, regiocontrolled Diels-Alder cycloaddition by prior selenosulfonation and oxidation to the vinyl sulfone.Reductive desulfonation after condensation with an activated diene provides th

Full text of DOI:10.1021/jo00149a035

Products guided by the article

Product name:3-(phenylsulfonyl)-2,5-dihydrofuran

Cas No:41649-12-1

R&D Labs maybe for 41649-12-1

Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Suzhou BEC Fine Chemicals Co., Ltd.

website:http://www.bek.com.cn

Contact:0512-68095917　 18913193865

Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside

Relevant to this article

A Facile, high-yield synthesis of trans-Fe(CO)₃(PR₃)₂ from Fe(CO)₅, Fe(CO)₄CHO^-, HFe(CO)₄^-, or HFe(CO)₃PR₃^-

Doi:10.1021/om00102a006
(1988)
Kinetics and Absorption Spectra of Transients in the Radiolysis of Hexafluorobenzene in Aqueous Solution: A Pulse Radiolysis Study

Doi:10.1021/j100104a019
(1993)
Artificial ribonucleases. 5. Synthesis and ribonuclease activity of tripeptides composed of amino acids involved in catalytic centers of natural ribonucleases

Doi:10.1023/B:RUCB.0000030824.26304.cb
(2004)
Synthesis and study of the behavior of glycosylated gemini surfactants in aqueous media

Doi:10.1039/b104958p
(2001)
Development of Covalent Ligands for G Protein-Coupled Receptors: A Case for the Human Adenosine A₃ Receptor

Doi:10.1021/acs.jmedchem.8b02026
(2019)
A mechanistic study of the reaction of phenyl isocyanate with methyl 2,3,4-tri-O-acetyl-α-D-glucopyranoside

Doi:10.1016/0008-6215(90)80027-Z
(1990)

Article Doi