An Indirect Method for Engaging Unactivated Alkenes as Effective Dienophiles in Regioselective Diels-Alder Reactions

DOI: 10.1021/jo00149a035

Source and publish data:

Journal of Organic Chemistry p. 141 - 142 (1983)

Update date:2022-08-04

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Authors:

Paquette, Leo A.

Crouse, Gary D.

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Article abstract of DOI:10.1021/jo00149a035

Terminal alkenes and cyclic olefins can be made to enter into efficient, regiocontrolled Diels-Alder cycloaddition by prior selenosulfonation and oxidation to the vinyl sulfone.Reductive desulfonation after condensation with an activated diene provides th

Full text of DOI:10.1021/jo00149a035

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