Tetrahedron Letters p. 6395 - 6398 (1993)
Update date:2022-08-04
Topics: Amines Nitriles one-step synthesis Copper(I)
Rousselet
Capdevielle
Maumy
Cu(I)Cl promotes the condensation of acetonitrile 1a and benzonitrile 1b with primary and secondary amines 2a-g into amidines 3a-j under mild conditions, in high to quantitative yields. Stoichiometric formation of Cu(I)-amidines complexes allows to control the degree of substitution of resulting amidines.
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Doi:10.1016/S0040-4020(02)00415-5
(2002)Doi:10.1002/hlca.19650480620
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(2015)Doi:10.1055/s-1973-22195
(1973)Doi:10.1021/ja01137a023
(1952)Doi:10.1055/s-1973-22198
(1973)
