Tetrahedron Letters p. 7901 - 7904 (1994)
Update date:2022-08-03
Topics:
Olson, Steven H.
Danishefsky, Samuel J.
The TMS-cyanohydrins of quinones undergo reductive desilanolation in the presence of samarium iodide to form hydroxybenzonitriles.Benzoquinone 1 was converted to the hexasubstituted aromatic fragment of calicheamicin 4 by this method.
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