Synthesis of arene Ti and Zr complexes and their reactivity towards air: crystal structure of (Al2Cl7) and TiCl3(OPh)

DOI: 10.1016/0022-328X(95)05438-U

Source and publish data:

Journal of Organometallic Chemistry p. C4 - C7 (1995)

Update date:2022-08-04

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Authors:

Troyanov, Sergei

Pisarevsky, Alex

Struchkov, Yuri T.

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Article abstract of DOI:10.1016/0022-328X(95)05438-U

The complex <(C6H3Me3)2Zr(μ-Cl)2AlCl2>(Al2Cl7) has been prepared by reductive Friedel-Crafts synthesis.Its structure confirms remarkable differences in chemistry of arene complexes of Ti(II) and Zr(II).The crystalline complex TiCl3(OPh) was formed by slow

Full text of DOI:10.1016/0022-328X(95)05438-U

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