Journal of Organometallic Chemistry p. 349 - 369 (1981)
Update date:2022-08-04
Topics:
Cuthbertson, Matthew J.
Wells, Peter R.
Rate data for the concurrent reaction of hexamethyldithin with dimethyltin dichloride and with stwo of the products of this reaction in methanol solution at 30 deg C have been analysed in terms of individual steps.Line-broadening phenomena in the system have been studied, providing evidence of the intermediacy of dimethyltin and its insertion into tin-chlorine bonds.A general mechanism for this and related reactions is presented.
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