Bulletin of the Chemical Society of Japan p. 2731 - 2733 (1990)
Update date:2022-08-03
Topics:
Shi, Min
Okamoto, Yoshiki
Takamuku, Setsuo
Upon UV irradiation in benzene-methanol (1:2) tetraarylmethanes or 3-(triarylmethyl)pyridines underwent an α,α-elimination of two aryl groups to give biaryls or 3-arylpyridine, and two corresponding carbene intermediates.The latters afforded methyl ethers by O-H insertion to methanol.
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