Partial Synthesis of Sesquiterpene Lactones: A Route to 7,11-Ene-13-hydroxyeudesmanolides

DOI: 10.1021/jo00011a025

Source and publish data:

Journal of Organic Chemistry p. 3587 - 3591 (1991)

Update date:2022-08-02

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Authors:

Collado, Gonzales

Madero, J. Gomez

Massanet, G. Martinez

Luis, F. Rodriguez

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Article abstract of DOI:10.1021/jo00011a025

An efficient partial synthesis of several sesquiterpene lactones has been carried out from costunolide by treatment with trimethyl(phenyl)ammonium perbromide.A selective bromination at the C-11 =C-13 bond provides a new route to 7,11-ene-13-hydroxyeudesmanolides.A synthesis of arbuscolin D has been achieved.

Full text of DOI:10.1021/jo00011a025

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