Journal of the Chemical Society, Dalton Transactions p. 212 - 218 (1981)
Update date:2022-07-29
Topics:
Dillon, Keith B.
Nisbet, Martin P.
Waddington, Thomas C.
The reactions of PPhO(OH)2 and PPhCl2O with the strongly acidic solvents 100percent H2SO4, 25 and 65 oleum, and HSClO3 have been investigated by means of 31P n.m.r. spectroscopy.Initial protonation of the phosphoryl oxygen, the extent of which varies with solute and solvent, is followed in most instances by sulphonation of the aromatic group (except in H2SO4), and/or condensation
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