Journal of the American Chemical Society p. 6863 - 6871 (1986)
Update date:2022-08-05
Topics:
Nelsen, Stephen F.
Kapp, Daniel L.
Akaba, Ryoichi
Evans, Dennis H.
Cyclic voltammetry studies allow estimation of the rate constant for addition of O2 to biadamantylidene cation radical (1.+) to be 5600 M-1 s-1 at room temperature and for the cleavage of biadamantylidene dioxetane cation radical to oxygen and 1.+ > 800 s-1.Chlorination of the adamantane skeleton slows the overall rate of oxygen addition, and the face selectivity for oxygenation of 5(Cl) is 25:1 in favor attack from the olefin face syn to the chlorine.The implications of these findings for the mechanism of the reaction are discussed.
View MoreTaizhou Elitechemie MediPharma Technology Co.,Ltd.
Contact:+86-523-86810021
Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Zhejiang Kaili Industrial Co., Ltd
Contact:+86-571-85241926
Address:lantian business center,No.18 Moganshan Road
Ningbo Inno Pharmchem Co., Ltd.
Contact:86-574-87319282
Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Hangzhou Bayee Chemical Co.,Ltd.
Contact:+86-571-86990109
Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Contact:+86-25-52346955
Address:199,JIANYE ROAD,NANJING,CHINA
Doi:10.1002/ejoc.202001313
(2020)Doi:10.1021/ja01162a031
(1950)Doi:10.1016/S0040-4020(03)00702-6
(2003)Doi:10.1080/10426509608029646
(1996)Doi:10.1021/jo00401a033
(1978)Doi:10.1016/0040-4039(93)85077-A
(1993)
