Journal of the American Chemical Society p. 6863 - 6871 (1986)
Update date:2022-08-05
Topics:
Nelsen, Stephen F.
Kapp, Daniel L.
Akaba, Ryoichi
Evans, Dennis H.
Cyclic voltammetry studies allow estimation of the rate constant for addition of O2 to biadamantylidene cation radical (1.+) to be 5600 M-1 s-1 at room temperature and for the cleavage of biadamantylidene dioxetane cation radical to oxygen and 1.+ > 800 s-1.Chlorination of the adamantane skeleton slows the overall rate of oxygen addition, and the face selectivity for oxygenation of 5(Cl) is 25:1 in favor attack from the olefin face syn to the chlorine.The implications of these findings for the mechanism of the reaction are discussed.
View MoreShangHai BMG Chemical Co., Ltd
Contact:+86-13524845543
Address:Room 602, no 291 sikai road shanghai
Tianjin Boron PharmaTech Co.,Ltd.(expird)
Contact:86-022-59845187
Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Contact:86-310-8067016
Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Zhejiang Tianyu Pharmaceutical Co., Ltd.
Contact:+86-576-84177669, 89189665,89189688,84168770
Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang
jiangsu senxuan pharmaceutical and chemical co.,ltd
Contact:86-523-87982810
Address:hongqiao industrial zone,taixing,jiangsu china
Doi:10.1002/ejoc.202001313
(2020)Doi:10.1021/ja01162a031
(1950)Doi:10.1016/S0040-4020(03)00702-6
(2003)Doi:10.1080/10426509608029646
(1996)Doi:10.1021/jo00401a033
(1978)Doi:10.1016/0040-4039(93)85077-A
(1993)