DIASTEREOSELECTIVITY IN THE TiCl4-MEDIATED ALDOL REACTION OF CYCLIC DIENYLSILYL ETHERS

DOI: 10.1016/S0040-4020(01)85123-1

Source and publish data:

Tetrahedron p. 6101 - 6112 (1989)

Update date:2022-08-03

Topics:

Authors:

Barner, Bruce A.

Liu, Yalei

Rahman, Md. Abdur

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Article abstract of DOI:10.1016/S0040-4020(01)85123-1

Cyclic dienylsilyl ethers derived from α,β-unsaturated ketones undergo TiCl4-catalyzed crossed aldol reactions with aldehydes, giving β'-hydroxy enone systems with good diastereoselectivity in most cases.The direction of stereocontrol (syn versus anti) in

Full text of DOI:10.1016/S0040-4020(01)85123-1

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