Cerium(III) Chloride Mediated Addition of Grignard Reagents to Nitroalkanes: Synthesis of N,N-Disubstituted Hydroxylamines

DOI: 10.1039/c39930001373

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1373 - 1374 (1993)

Update date:2022-07-31

Topics:

Authors:

Bartoli, Giuseppe

Marcantoni, Enrico

Petrini, Marino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001373

Reaction of nitroalkanes with Grignard reagents, in the presence of anhydrous CeCl3 in tetrahydrofuran at -78 degC, affords N,N-disubstituted hydroxylamines in fair to good yields, depending on the nature of the reagent used.

Full text of DOI:10.1039/c39930001373

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cyclohexanamine, N-hydroxy-N-propyl-

Cas No:65616-24-2

R&D Labs maybe for 65616-24-2

Chengdu Pukang Biotechnology Co., Ltd

website:http://www.pu-kang.com

Contact:86-028-63976226

Address:No. 868 Xiwang Road,Xinjin county,Chengdu city, China
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD

Contact:86-0951-7815345

Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China

Relevant to this article

Structure and activity relationships of novel uracil derivatives as topical anti-inflammatory agents

Doi:10.1016/j.bmc.2003.09.012
(2003)
Toward a prostate specific antigen-based prostate cancer diagnostic assay: Preparation of keyhole limpet hemocyanin-conjugated normal and transformed prostate specific antigen fragments

Doi:10.1021/ja8028137
(2008)
Ruthenium-Catalyzed Dehydrogenative N-Heterocyclization: Indoles from 2-Aminophenethyl Alcohols and 2-Nitrophenethyl Alcohols

Doi:10.1021/jo00289a036
(1990)
Doi:10.1021/ja00470a029
(1978)
SYNTHESIS AND PROPERITES OF 7-(1,3-DITHIOL-2-YLIDENE)-3,5-CYCLOHEPTADIENE-1,2-DIONE (OR 7,10-DITHIASESQUIFULVALENE-1,2-QUINONE) DERIVATIVES

Doi:10.1246/cl.1981.805
(1981)
Novel modified tripeptide inhibitors of α₄β₇ mediated lymphoid cell adhesion to MAdCAM-1

Doi:10.1016/S0960-894X(98)00286-8
(1998)

Article Doi