Cerium(III) Chloride Mediated Addition of Grignard Reagents to Nitroalkanes: Synthesis of N,N-Disubstituted Hydroxylamines

DOI: 10.1039/c39930001373

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1373 - 1374 (1993)

Update date:2022-07-31

Topics:

Authors:

Bartoli, Giuseppe

Marcantoni, Enrico

Petrini, Marino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001373

Reaction of nitroalkanes with Grignard reagents, in the presence of anhydrous CeCl3 in tetrahydrofuran at -78 degC, affords N,N-disubstituted hydroxylamines in fair to good yields, depending on the nature of the reagent used.

Full text of DOI:10.1039/c39930001373

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cyclohexanamine, N-hydroxy-N-propyl-

Cas No:65616-24-2

R&D Labs maybe for 65616-24-2

Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

website:http://www.jlpharms.com

Contact:86-571-86982636

Address:Rm A606, Fuyi Center, jianqiao street
Xi'an Herbland Tech Inc.

Contact:+86-29-88710656

Address:South Tai bai Road, High Tech Development Zone, Xi'an China
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
Nanjing Qirui Material Co., Ltd.

Contact:+86-25-52320053

Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300

Relevant to this article

Structure and activity relationships of novel uracil derivatives as topical anti-inflammatory agents

Doi:10.1016/j.bmc.2003.09.012
(2003)
Toward a prostate specific antigen-based prostate cancer diagnostic assay: Preparation of keyhole limpet hemocyanin-conjugated normal and transformed prostate specific antigen fragments

Doi:10.1021/ja8028137
(2008)
Ruthenium-Catalyzed Dehydrogenative N-Heterocyclization: Indoles from 2-Aminophenethyl Alcohols and 2-Nitrophenethyl Alcohols

Doi:10.1021/jo00289a036
(1990)
Doi:10.1021/ja00470a029
(1978)
SYNTHESIS AND PROPERITES OF 7-(1,3-DITHIOL-2-YLIDENE)-3,5-CYCLOHEPTADIENE-1,2-DIONE (OR 7,10-DITHIASESQUIFULVALENE-1,2-QUINONE) DERIVATIVES

Doi:10.1246/cl.1981.805
(1981)
Novel modified tripeptide inhibitors of α₄β₇ mediated lymphoid cell adhesion to MAdCAM-1

Doi:10.1016/S0960-894X(98)00286-8
(1998)

Article Doi