Cerium(III) Chloride Mediated Addition of Grignard Reagents to Nitroalkanes: Synthesis of N,N-Disubstituted Hydroxylamines

DOI: 10.1039/c39930001373

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1373 - 1374 (1993)

Update date:2022-07-31

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Authors:

Bartoli, Giuseppe

Marcantoni, Enrico

Petrini, Marino

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Article abstract of DOI:10.1039/c39930001373

Reaction of nitroalkanes with Grignard reagents, in the presence of anhydrous CeCl3 in tetrahydrofuran at -78 degC, affords N,N-disubstituted hydroxylamines in fair to good yields, depending on the nature of the reagent used.

Full text of DOI:10.1039/c39930001373

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