Biomacromolecules
Article
effectiveness of cationic polymer as a compatibilizer in microfibrillated
cellulose-reinforced polyolefins. Cellulose 2016, 23, 623−635.
(23) Liu, A.; Walther, A.; Ikkala, O.; Belova, L.; Berglund, L. A. Clay
nanopaper with tough cellulose nanofiber matrices for fire retardancy
and gas barrier functions. Biomacromolecules 2011, 12, 633−641.
(24) Gabr, M. H.; Phong, N. T.; Abdelkareem, M. A.; Okubo, K.;
Uzawa, K.; Kimpara, I.; Fujii, T. Mechanical, thermal, and moisture
absorption properties of nano-clay reinforced nano-cellulose bio-
composites. Cellulose 2013, 20, 819−826.
(42) Wada, M.; Heux, L.; Sugiyama, J. Polymorphism of cellulose I
family: Reinvestigation of cellulose IV. Biomacromolecules 2004, 5,
1385−1391.
(43) Liao, Y. Y.; Picot, P.; Brubach, J. B.; Roy, P.; Thill, A.; Le Caer,
S. Water Adsorption in Single-and Double-Walled Inorganic Nano-
̀
(44) Amara, M. S.; Rouziere, S.; Paineau, E.; Bacia-Verloop, M.;
Thill, A.; Launois, P. Hexagonalization of aluminogermanate
imogolite nanotubes organized into closed-packed bundles. J. Phys.
Chem. C 2014, 118, 9299−9306.
(25) Wang, J.; Cheng, Q.; Lin, L.; Jiang, L. Synergistic toughening of
bioinspired poly (vinyl alcohol)−clay−nanofibrillar cellulose artificial
nacre. ACS Nano 2014, 8, 2739−2745.
(45) Li, L. L.; Fan, H. L.; Wang, L.; Jin, Z. X. Does halloysite behave
like an inert carrier for doxorubicin? RSC Adv. 2016, 6, 54193−54201.
(46) Ma, W.; Kim, J.; Otsuka, H.; Takahara, A. Surface modification
of individual imogolite nanotubes with alkyl phosphate from an
aqueous solution. Chem. Lett. 2011, 40, 159−161.
(26) Cavallaro, G.; Lazzara, G.; Konnova, S.; Fakhrullin, R.; Lvov, Y.
Composite films of natural clay nanotubes with cellulose and chitosan.
Green Mater. 2014, 2, 232−242.
(47) Maduskar, S.; Maliekkal, V.; Neurock, M.; Dauenhauer, P. J. On
the yield of levoglucosan from cellulose pyrolysis. ACS Sustainable
Chem. Eng. 2018, 6, 7017−7025.
(48) Yamamoto, K.; Otsuka, H.; Wada, S. I.; Sohn, D.; Takahara, A.
Transparent polymer nanohybrid prepared by in situ synthesis of
aluminosilicate nanofibers in poly (vinyl alcohol) solution. Soft Matter
2005, 1, 372−377.
(49) Toivonen, M. S.; Kurki-Suonio, S.; Schacher, F. H.; Hietala, S.;
Rojas, O. J.; Ikkala, O. Water-resistant, transparent hybrid nanopaper
by physical cross-linking with chitosan. Biomacromolecules 2015, 16,
1062−1071.
(50) Araujo, C.; Freire, C. S. R.; Nolasco, M. M.; Ribeiro-Claro, P.
J.; Rudic, S.; Silvestre, A. J.; Vaz, P. D. Hydrogen bond dynamics of
cellulose through inelastic neutron scattering spectroscopy. Bioma-
cromolecules 2018, 19, 1305−1313.
(27) Wu, C. N.; Saito, T.; Fujisawa, S.; Fukuzumi, H.; Isogai, A.
Ultrastrong and high gas-barrier nanocellulose/clay-layered compo-
sites. Biomacromolecules 2012, 13, 1927−1932.
(28) Farmer, V. C.; Fraser, A. R.; Tait, J. M. Synthesis of imogolite: a
tubular aluminium silicate polymer. J. Chem. Soc., Chem. Commun.
1977, No. 13, 462−463.
́
(29) Gonzalez del Campo, M.; Darder, M.; Aranda, P.; Akkari, M.;
Huttel, V.; Mayoral, A.; Bettini, J.; Ruiz-Hitzky, E. Functional Hybrid
Nanopaper by Assembling Nanofibers of Cellulose and Sepiolite. Adv.
Funct. Mater. 2018, 28, 1703048.
̈
(30) Wicklein, B.; Diem, A. M.; Knoller, A.; Cavalcante, M. S.;
̈
Bergstrom, L.; Bill, J.; Burghard, Z. Dual-Fiber Approach toward
Flexible Multifunctional Hybrid Materials. Adv. Funct. Mater. 2018,
28, 1704274.
(31) Rezayati Charani, P.; Dehghani-Firouzabadi, M.; Afra, E.;
Shakeri, A. Rheological Characterization of High Concentrated MFC
Gel from Kenaf Unbleached Pulp. Cellulose 2013, 20, 727−740.
(51) Benítez, A. J.; Torres-Rendon, J.; Poutanen, M.; Walther, A.
Humidity and multiscale structure govern mechanical properties and
deformation modes in films of native cellulose nanofibrils.
Biomacromolecules 2013, 14, 4497−450.
̈
̈
̈
̈
(32) Paakko, M.; Ankerfors, M.; Kosonen, H.; Nykanen, A.; Ahola,
S.; Osterberg, M.; Ruokolainen, J.; Laine, J.; Larsson, P. T.; Ikkala, O.;
̈
Lindstrom, T. Enzymatic Hydrolysis Combined with Mechanical
Shearing and High-Pressure Homogenization for Nanoscale Cellulose
Fibrils and Strong Gels. Biomacromolecules 2007, 8, 1934−1941.
(33) Li, M. C.; Wu, Q.; Song, K.; Lee, S.; Qing, Y.; Wu, Y. Cellulose
nanoparticles: structure−morphology−rheology relationships. ACS
Sustainable Chem. Eng. 2015, 3, 821−832.
(34) Kondo, T.; Sawatari, C.; Manley, R. S. J.; Gray, D. G.
Characterization of hydrogen bonding in cellulose-synthetic polymer
blend systems with regioselectively substituted methylcellulose.
Macromolecules 1994, 27, 210−215.
(35) Mukai, M.; Ma, W.; Ideta, K.; Takahara, A. Preparation and
Characterization of Boronic Acid- Functionalized Halloysite Nano-
tube/Poly(vinyl alcohol) Nanocomposites. Polymer 2019, 178,
121581.
(36) Peng, C.; Dong, B.; Zhang, C.; Hu, Y.; Liu, L.; Zhang, X. A
Host−Guest Interaction Assisted Approach for Fabrication of
Polybutadiene Nanocomposites Reinforced with Well-Dispersed
Cellulose Nanocrystals. Macromolecules 2018, 51, 4578−4587.
(37) Sehaqui, H.; Zhou, Q.; Berglund, L. A. Nanostructured
biocomposites of high toughnessa wood cellulose nanofiber
network in ductile hydroxyethylcellulose matrix. Soft Matter 2011,
7, 7342−7350.
(38) Wada, S. I.; Wada, K. Density and structure of allophane. Clay
Miner. 1977, 12, 289−298.
(39) Yano, H.; Nakahara, S. Bio-composites produced from plant
microfiber bundles with a nanometer unit web-like network. J. Mater.
Sci. 2004, 39, 1635−1638.
(40) Li, L. L.; Ma, W.; Higaki, Y.; Kamitani, K.; Takahara, A.
Organic-Inorganic Hybrid Thin Film Fabricated by Layer-by-Layer
Assembly of Phosphorylated Cellulose Nanocrystal and Imogolite
Nanotubes. Langmuir 2018, 34, 13361−13367.
(41) Chen, W.; Yu, H.; Liu, Y.; Chen, P.; Zhang, M.; Hai, Y.
Individualization of cellulose nanofibers from wood using high-
intensity ultrasonication combined with chemical pretreatments.
Carbohydr. Polym. 2011, 83, 1804−1811.
3574
Biomacromolecules 2019, 20, 3566−3574