CARBOCATIONIC CYCLISATIONS AND REARRANGEMENTS IN THE DAMASCONE SERIES

DOI: 10.1016/S0040-4020(01)89793-3

Source and publish data:

Tetrahedron p. 6047 - 6054 (1988)

Update date:2022-08-06

Topics:

Authors:

Heilmann, Werner

Azizur-Rahman

Baeuml, Englbert

Mayr, Herbert

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Article abstract of DOI:10.1016/S0040-4020(01)89793-3

A regio- and stereoselective synthesis of the tertiary chloride 7 is described, involving the Lewis acid catalysed addition of the allyl chloride 6 to isobutene as a key step.Acid catalysed cyclisation of 7 yields the damasconoid compounds 12-15.

Full text of DOI:10.1016/S0040-4020(01)89793-3

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