Journal of the Chemical Society. Chemical communications p. 1699 - 1700 (1995)
Update date:2022-08-04
Topics:
Huang, Xiaoming
Harris, Thomas M.
The title compound, the most important genotoxic metabolite of benzopyrene, has been prepared efficiently in a synthesis which capitalized on Jacobsen-type enantioselective epoxidation of 9,10-dihydrodibenzopyrene, cleavage of the epoxide by KOH-Me2SO to give the tetrahydro-trans-7,8-diol, and formation of the dibenzoate from which the contaminating antipode was removed by crystallization.
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Doi:10.1002/chem.201703513
(2018)Doi:10.1016/j.bmcl.2004.01.056
(2004)Doi:10.1002/recl.19951141108
(1995)Doi:10.1039/c5cc04723d
(2015)Doi:10.1021/ja028659n
(2002)Doi:10.1016/j.poly.2003.11.048
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