Tetrahedron Letters p. 8733 - 8736 (1995)
Update date:2022-07-30
Topics: Steric Effects Solvent Effects Catalysis Competing Reactions
Springer
Springer, James B.
DeBoard
Deboard, Julie
Corcoran
Corcoran, Robert C.
The diastereoselectivities of addition reactions of allyltrimethylsilane to an α-benzyloxyaldehyde were found to be relatively insensitive to the amount of added TiCl4, and to the absolute concentration of the 1:1 aldehyde/TiCl4 complex. In contrast, diastereoselectivities of similar additions to a structurally related β-benzyloxyaldehyde were highly dependent on these variables.
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