
Journal of Organic Chemistry p. 891 - 894 (1980)
Update date:2022-08-05
Topics:
Arnold, Richard T.
Kulenovic, Srdanka T.
Several cases of the oxy-Cope rearrangement, which typically prefers the <3,3>-sigmatropic route, are now known to occur in a <1,3>-sigmatropic fashion.By contrast, the symmetry-allowed thermal rearrangement of carbanions (or their enol derivatives; e.g.,
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