Organic Fluorine Compounds. 32. A 1,3-Dipolar Cycloaddition Reaction of Tetrakis(trifluoromethyl)(Dewar Thiophene) and Some Reactions of the Cycloadducts

DOI: 10.1021/jo01303a009

Source and publish data:

Journal of Organic Chemistry p. 2962 - 2966 (1980)

Update date:2022-09-26

Topics:

Authors:

Kobayashi, Yoshiro

Ando, Akira

Kawada, Kosuke

Ohsawa, Akio

Kumadaki, Itsumaro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01303a009

The reaction of tetrakis(trifluoromethyl)(Dewar thiophene) (1) with azide compounds 2, including hydrogen azide, gave high yields of 1,3-dipolar cycloadducts 3.Compounds 3a-d were desulfurized with triphenylphosphine to afford cyclobutatriazoline compound

Full text of DOI:10.1021/jo01303a009

Products guided by the article

Product name:[(Z)-4-Diazo-5,5,5-trifluoro-1,2,3-tris-trifluoromethyl-pent-2-en-(Z)-ylidene]-phenyl-amine

Cas No:73688-35-4

R&D Labs maybe for 73688-35-4

Neworld Chemical Co., Ltd Shanghai(expird)

Contact:+86-21-62202658

Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Nanjing Chemzam Pharmtech Co., Ltd.

Contact:+86-25-86462165,+86-13915979898

Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong

Relevant to this article

The Co(I) induced methylmalonyl-succinyl rearrangement in a model for the coenzyme B12 dependent methylmalonyl-CoA mutase.

Doi:10.1039/b305782h
(2003)
Addition/elimination reactions of ethylsulfonyl pyridines: Stereoselective synthesis of vinylpyridine allylic alcohols

Doi:10.1016/j.tetlet.2012.12.049
(2013)
Doi:10.1016/S0040-4039(01)86556-4
(1979)
2-[2-(4-Methoxyphenyltelluro)ethyl]thiophene (L¹) bis[2-(2-thienyl)ethyl] telluride (L²) and their metal complexes; crystal structure of trans-dichlorobis{2-(2- (4-methoxyphenyltelluro)ethyl)thiophene-Te}palladium(II) and {bis[2-(2-thienyl)ethyl] telluride}dichloro(p-cymene)ruthenium(II)

Doi:10.1016/j.jorganchem.2004.04.023
(2004)
Doi:10.1007/BF00901733
(1964)
Synthesis and actin-depolymerizing activity of mycalolide analogs

Doi:10.1016/j.tetlet.2004.05.078
(2004)

Article Doi