Synthesis p. 2619 - 2622 (2005)
Update date:2022-08-03
Topics:
Oller-Lopez, Juan L.
Campana, Araceli G.
Cuerva, Juan M.
Oltra, J. Enrique
A novel procedure for the reduction and pinacol coupling of aromatic aldehydes and ketones mediated by titanocene(III)/Zn in water is described. The titanocene-catalyzed version in sea water proved to be especially convenient for the reduction of aryl ketones. Mechanistically, the reaction presumably proceeds via free-radical chemistry. Georg Thieme Verlag Stuttgart.
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