Electron Spin Resonance Studies. Part 58. The Formation and Reactions of Some Aliphatic Radical-cations in Aqueous Solution

DOI: 10.1039/P29800000647

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 647 - 656 (1980)

Update date:2022-08-04

Topics:

Authors:

Gilbert, Bruce C.

Norman, Richard O.C.

Williams, Peter S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29800000647

Evidence is presented that reaction of Cl2^-. with vinyl ethers proceeds via the formation of the radical-cations of the parent compounds.These species are not directly detectable by e.s.r., but the spectra of radicals formed in one or more of three further reactions have been characterized.These reactions are hydration, addition to the parent molecule, and deprotonation +. (from ethyl vinyl ether) yields the hydroxylated radicals ^.CH(OEt)CH2OH and ^.CH2CH(OH)OEt and the 'dimer' radical ^.CH(OEt)CH2CH2CH(OH)OEt>.It has been confirmed that analogous radical-cations are also formed during the reactions of the hydroxyl radical with enol ethers at low pH and by elimination reactions of radicals of the type ^.CH(OR)CH2X (with X = Cl, OH, or OMe).It is shown that furan is an effective spin trap for the radical-cations involved in these reactions.

Full text of DOI:10.1039/P29800000647

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₈H₁₃O₃

Cas No:74218-01-2

R&D Labs maybe for 74218-01-2

Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
Forsman Scientific(Beijing)co.,Ltd.

Contact:+86-10-64646565

Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,

Relevant to this article

Doi:10.1016/S0040-4039(01)86745-9
(1979)
Unusual carbon-carbon bond formations between allylboronates and acetals or ketals catalyzed by a peculiar indium(I) lewis acid

Doi:10.1021/ol100450s
(2010)
Metabolites of microorganisms, 189 - Structure elucidation and partial synthesis of the nucleoside antibiotic nikkomycin B

Doi:10.1002/jlac.198019800414
(1980)
Synthesis of oligodeoxynucleotides containing a single diastereoisomer of α-(N²-2′-deoxyguanosinyl)-N-desmethyltamoxifen

Doi:10.1016/j.bmcl.2004.05.030
(2004)
A reactive and environmentally friendly protocol for expeditious synthesis of various resorcinarenes using zinc hydrogen sulfate

Doi:10.1080/10610278.2019.1598557
(2019)
A rapid and convenient synthesis of derivatives of imidazoles under Microwaveirradiation

Doi:10.1002/jccs.200500078
(2005)

Article Doi